Regio- and stereoselective hydrosilylation of terminal alkynes using Grubbs' first-generation olefin-metathesis catalyst
- 13 August 2004
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Organic & Biomolecular Chemistry
- Vol. 2 (18) , 2558-2562
- https://doi.org/10.1039/b409832c
Abstract
Grubbs' first-generation, Ru metathesis complex 3 catalyses the hydrosilylation of terminal alkynes. The reaction exhibits an interesting selectivity profile that is dependent on the reaction concentration and more importantly on the silane employed.Keywords
This publication has 47 references indexed in Scilit:
- Cross-Coupling Reactions of Alkenylsilanolates. Investigation of the Mechanism and Identification of Key Intermediates through Kinetic AnalysisJournal of the American Chemical Society, 2004
- Fluoride-Promoted Cross-Coupling Reactions of Alkenylsilanols. Elucidation of the Mechanism through Spectroscopic and Kinetic AnalysisJournal of the American Chemical Society, 2004
- Design and Implementation of New, Silicon-Based, Cross-Coupling Reactions: Importance of Silicon−Oxygen BondsAccounts of Chemical Research, 2002
- Organosilicon CompoundsPublished by Springer Nature ,2002
- Direct Carbonylation at a C−H Bond in the Benzene Ring of 2-Phenyloxazolines Catalyzed by Ru3(CO)12. Scope, Limitations, and Mechanistic AspectsThe Journal of Organic Chemistry, 2000
- Stereochemical Control in Organic Synthesis Using Silicon-Containing CompoundsChemical Reviews, 1997
- Uses of Silicon-Containing Compounds in the Synthesis of Natural ProductsChemical Reviews, 1995
- The Electrophilic Substitution of Allylsilanes and VinylsilanesPublished by Wiley ,1989
- Vinylsilane- and alkynylsilane-terminated cyclization reactionsChemical Reviews, 1986
- Electrophilic Substitution of Organosilicon Compounds- Applications to Organic SynthesisSynthesis, 1979