Mechanism of initiation of cumene autoxidation by palladium(0) complexes
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 15,p. 788b-789
- https://doi.org/10.1039/c2971000788b
Abstract
Chain initiation in the liquid-phase autoxidation of cumene at 35° catalysed by the palladium(0) complex (Ph3P)4Pd, occurs via hydroperoxide decomposition and not via an “oxygen activation” mechanism.Keywords
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