Note on Pressure Effects in Band Spectra
- 15 April 1936
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 49 (8) , 596-597
- https://doi.org/10.1103/physrev.49.596
Abstract
A simple theory is presented describing pressure effects on band lines, insofar as they are due to foreign perturbing molecules without permanent polarity. Results are: Band lines are shifted and broadened much in the manner of atomic lines as a result of van der Waals interactions. Calculations with the models of a rigid rotator and a simple harmonic oscillator, for which formulas are given, show that the effects are practically independent of rotational and vibrational quantum numbers.Keywords
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