A Three-Dimensional Coordination Polymer with an Expanded NbO Structure
- 12 July 1999
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (13-14) , 1934-1937
- https://doi.org/10.1002/(sici)1521-3773(19990712)38:13/14<1934::aid-anie1934>3.0.co;2-n
Abstract
The connection of square-planar [Ni(CN)4]2− ions with Ph3Sn+ ions results in 1, a noninterpenetrated three-dimensional coordination polymer with an expanded NbO structure. The (Ph3Sn)2Ni(CN)4 framework (shown schematically without phenyl groups and solvent molecules) displays a large central cavity that is occupied by Ph3SnOH, acetonitrile, and water molecules.This publication has 0 references indexed in Scilit: