The First Examples of Metallatricarbollides. Isomeric Twelve-Vertex Cyclopentadienyl Ferratricarbadodecaboranes [(η5-C5H5)-closo-FeC3B8H11]
- 1 January 1995
- journal article
- Published by Institute of Organic Chemistry & Biochemistry in Collection of Czechoslovak Chemical Communications
- Vol. 60 (12) , 2023-2027
- https://doi.org/10.1135/cccc19952023
Abstract
The first metallatricarbollides, six isomeric twelve-vertex metallatricarbaboranes of general structure [(η5-C5H5)-closo-FeC3B8H11], are formed in the reaction between TI[nido-7,8,9-C3B8H11] and [(η5-C5H5)- Fe(CO)2I] in toluene at reflux. Two of them have so far been satisfactorily identified as [3-(η5-C5H5)-closo-3,1,2,4-FeC3B8H11] and [2-(η5-C5H5)-closo-2,1,8,11-FeC3B8H11] by NMR spectroscopy.Keywords
This publication has 0 references indexed in Scilit: