Chiral pyridylimidazolines: synthesis, arene ruthenium complexes and application in asymmetric catalysis
- 13 June 2001
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 13,p. 1500-1503
- https://doi.org/10.1039/b103175a
Abstract
Condensation of (1S,2S)-1,2-diphenylethylenediamine and 2-cyanopyridine gives the chiral pyridylimidazoline (L1), deprotonation followed by treatment with methyl iodide gives an NMe derivative (L2). The pyridylimidazolines react with [RuCl2(mes)]2 (mes = 1,3,5-trimethylbenzene) in the presence of NaSbF6 to give [RuCl(L)(mes)][SbF6] (1,2) which have been characterised by X-ray crystallography. After treatment with AgSbF6 both complexes are enantioselective catalysts for the Diels–Alder reaction of methacrolein and cyclopentadiene.Keywords
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