The preparation and structure of [Co3(η-C5H5)3(µ3-CNC6H11)(µ3-S)]; the first example of an organoisocyanide as a triply bridging, two-electron donor ligand
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1071-1072
- https://doi.org/10.1039/c39830001071
Abstract
The reaction of [Co(η-C5H5)(Co)(PPh3)] with RNCS in refluxing benzene gives [Co(η-C5H5)(PPh3)(η2-PhNCS-C,S)] and [Co3(η-C5H5)3(µ3-CNR)(µ3-S)](2)(R = Me, C6H11, or Ph); the structure of (2; R = C6H11) has been determined by an X-ray diffraction study.Keywords
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