Unusual bonding in bicyclotetrasilane vs. bicyclobutane: a theoretical study
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 896-898
- https://doi.org/10.1039/c39860000896
Abstract
Bicyclotetrasilane, compared with its carbon analogue bicyclobutane, has an unusually labile central bond; the ring strain energies are comparable, but the ring separation energies opposite in sign.Keywords
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