Soft X-Ray Absorption Edges of Metal Ions in Complexes. II. Cu K Edge in Some Cupric Complexes

1 October 1956

journal article
conference paper
Published by AIP Publishing in The Journal of Chemical Physics

Vol. 25 (4) , 619-623
https://doi.org/10.1063/1.1743012

Abstract

It is shown that the crystal field splitting of the 4p orbitals of Cu(II) in some complexes can be correlated with the splitting of the 1s—4p transition observed in studies of the K absorption edges of these complexes, provided the ligand‐metal bonding is not appreciably covalent.

Keywords

This publication has 14 references indexed in Scilit:

The crystal structure of cupric tetrammine sulfate monohydrate, Cu(NH3)4SO4.H2O
Acta Crystallographica, 1955
X-Ray Spectroscopy of the Solid State: Potassium Chloride
Physical Review B, 1955
The crystal structure of copper proline dihydrate
Acta Crystallographica, 1952
The Cu $K$ Absorption Edges of the Cuprous Halides
Physical Review B, 1945
The $K$ -Absorption Edges of Metal Ions in Aqueous Solution
Physical Review B, 1942
Copper and Nickel X-Ray $K β_{2}$ - and $K β_{5}$ -Emission Lines and $K$ -Absorption Limits in Cu-Ni Alloys
Physical Review B, 1940
The X-Ray $K$ Absorption Edges of the Elements Fe (26) to Ge (32)
Physical Review B, 1939
X-Ray Resonance Absorption Lines in the Argon $K$ Spectrum
Physical Review B, 1939
The soft x-ray spectroscopy of the solid state
Reports on Progress in Physics, 1938
The crystal structure of copper sulphate pentahydrate, CuSO ₄ .5H ₂ O
Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character, 1934