Photoelectrochemical Properties of Thin Films of Cadmium, Zinc, and Magnesium Porphyrins with Pyridyl Group

Abstract
Cadmium and zinc porphyrins with pyridyl or aminophenyl group gave smaller activation energy for the transfer of the carriers photoproduced in the solid thin film and larger cathodic photocurrent in quinhydrone solution than tetraphenylporphyrinato-cadmium and -zinc. The properties may be ascribed to the molecular arrangement of the porphyrins in the film

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