A photochemical study of rotational state dependence by laser excitation of formaldehyde (? 1A2). I. Coriolis and singlet–triplet perturbation
- 1 April 1977
- journal article
- letter
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 66 (7) , 3303-3305
- https://doi.org/10.1063/1.434308
Abstract
A study of rotational dependence of radiationless transition rate and radical yield in the photodecomposition of formaldehyde, H2CO(? 1S2), was made with laser‐induced fluorescence excitation spectroscopy and chemiluminescence excitation spectroscopy [Lewis, Tang and Lee, J. Chem. Phys., 65, 2910 (1976)]. The effect of perturbations on some rovibronic levels excited by the 220410 and 230410 transitions is examined.Keywords
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