Stereoselective synthesis of α,β-unsaturated esters
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 877-878
- https://doi.org/10.1039/c39810000877
Abstract
Reaction of α-silylated ester magnesium enolates with aldehydes affords exclusively one diastereoisomer of the two possible β-hydroxy silanes which give pure E-unsaturated esters on acid work-up.Keywords
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