Ionization potentials, electron affinities and screening constants. Part 7.—Comparison with Hartree-Fock calculations
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 64, 1742-1746
- https://doi.org/10.1039/tf9686401742
Abstract
This paper continues, by considering recent Hartree-Fock calculations, the discussion of the present theory of screening-constants Σ. The assumption of a slight variation of Σ with inverse powers of atomic number brings together the facts and the various theories. Good agreement is thus obtained between the present theory and perturbation-calculations, both then showing small systematic differences from the Hartree-Fock results.Keywords
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