Highly Stereoselective Introduction of Fluorine-Containing Methyl Groups at 2 Position of D-Glucose
- 1 June 1997
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1997 (6) , 669-670
- https://doi.org/10.1055/s-1997-3264
Abstract
Highly stereoselective introduction of fluorine-containing methyl groups at the 2 position of methyl glucoside was attained by use of the difluoromethylene derivative as a key intermediate via hydrogenation of exo- and endo-olefins, whose diastereofacial selectivity was considered to be governed by the anomeric methoxy group.Keywords
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