Stereochemical studies of optically active 2-hydroxy-5-alkyl-δ-valerolactone derivatives as chiral dopant for ferroelectric liquid crystals

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Abstract
Both (2S, 5R)- and (2R, 5R)-2-hydroxy-5-alkyl-δ-valerolactone derivatives, cis and trans, respectively, show almost the same magnitude of spontaneous polarization (P s) when added to a non-chiral smectic C mixture. The stereochemistry of these chiral dopants was studied using 1H NMR. Trans derivatives seem to have a half-chair conformation with the 2, 5-diequatorial substituents and the cis derivatives have rather a flat conformation in solution. However in the liquid-crystalline phase, the cis and trans derivatives appear to change their conformation or the distribution of their conformations as the alkyl chain length is varied. The difference in the effect as a chiral dopant depends upon lateral interactions between chiral molecules through the solvent liquid crystal phase.