Selective total synthesis of (±)-α- and γ-polypodatetraene
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 467-468
- https://doi.org/10.1039/c39840000467
Abstract
The fern metabolites, α-and γ-polypodatetraene, possible biosynthetic intermediates of onocerane type triterpenoids, are selectively synthesized by mercury(II) trifluoromethanesulphonate–amine complex-induced olefin cyclization followed by simple chemical transformations.Keywords
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