Novel heterocycles: an unexpected facile methylation of aluminium by a methyl-silane functionality and formation of a novel ylidic heterocycle
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1621-1622
- https://doi.org/10.1039/c39900001621
Abstract
From AlCl3 and Li[C(PMe2)(SiMe3)2] in a 1:2 stoichiometric ratio a novel heterocycle (Me)(Cl)A[graphic ommitted]Me24, exhibiting a number of unusual features, is obtained by methyl migration from silicon to aluminium.Keywords
This publication has 1 reference indexed in Scilit:
- Ligandenaustauschreaktionen zwischen Halogenboranen und Alkylsilanen/Ligand Exchange Reactions between Haloboranes and AlkylsilanesZeitschrift für Naturforschung B, 1990