Reactivity of ethylenic compounds: bromination reaction. Solvation and charge development in the transition state of Ad E C1 mechanism in hydroxylic solvents
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 15,p. 829-830
- https://doi.org/10.1039/c29710000829
Abstract
An analysis of the secondary solvent isotope effect and of the solvent effect in methanol–water mixtures on the rate of bromination of pent-1-ene indicates that the transition state for this reaction is highly polarized and essentially solvated through hydrogen bonding.Keywords
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