Optical and Electrical Properties of Single Crystals of Tri-p-Methoxy Phenyl Methyl Perchlorate and Triphenyl Methyl Azide
- 1 June 1959
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 30 (6) , 1437-1442
- https://doi.org/10.1063/1.1730218
Abstract
Measurements have been made of the optical and electrical properties of single crystals of tri‐p‐methoxy phenyl methyl perchlorate and triphenyl methyl azide. These include the absorption spectra, photoconduction behavior, low‐frequency dielectric constants, and refractive indices. In the case of tri‐p‐methoxy phenyl methyl perchlorate where the electron affinity of the acid radical is high the solid is ionic and an estimate has been made of the energy required to raise an electron from the full band to the conduction band. The properties of triphenyl methyl azide are consistent with a covalent type solid. The stability of these compounds is considered in outline.Keywords
This publication has 14 references indexed in Scilit:
- Structure and stability of inorganic azides. II. Some physical and optical properties, and the fast decomposition of solid monovalent inorganic azidesProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1959
- Lattice energies and related properties derived using lyotropic numbersJournal of Inorganic and Nuclear Chemistry, 1958
- The optical and electrical properties of silver azide and their relation to its decompositionProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1957
- Photographic sensitivityReports on Progress in Physics, 1957
- Fundamental vibration frequencies and force constants in the azide ionTransactions of the Faraday Society, 1957
- The Absorption Spectra of Single Crystals of Pure and Partially Decomposed Silver AzideProceedings of the Physical Society. Section B, 1957
- Photoconductivity of Some Cyanine Dyes*Journal of the Optical Society of America, 1956
- Aryl Carbonium Ions in Sulfuric Acid1Journal of the American Chemical Society, 1951
- An X-Ray Examination of Crystals of Triphenylmethyl Chloride and BromideJournal of the American Chemical Society, 1944
- THE QUINONOID STRUCTURE OF SOME TRIPHENYLMETHYL SALTSJournal of the American Chemical Society, 1930