Palladium-catalysed desulphonylative vinylation of arenesulphonyl chlorides under solid–liquid phase-transfer conditions
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 8,p. 2207-2211
- https://doi.org/10.1039/p19900002207
Abstract
The reaction of arenesulphonyl chlorides (1a–n) with butyl acrylate (2a) in the presence of a catalytic amount of bis(benzonitrile)dichloropalladium [PdCl2(PhCN)2] under solid–liquid phase-transfer conditions gave the corresponding butyl (E)-3-arylprop-2-enoates (3a–n) in good yield. The alkenes (2b–g) could also be used in place of (2a).Keywords
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