A Solution-Phase Chemical Approach to a New Crystal Structure of Cobalt
- 14 June 1999
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (12) , 1788-1791
- https://doi.org/10.1002/(sici)1521-3773(19990614)38:12<1788::aid-anie1788>3.0.co;2-2
Abstract
Kinetic control of crystal growth in the presence of a coordinating ligand is critical for the formation of a new structure of elemental cobalt (ε-cobalt, the unit cell with the two different types of cobalt atoms is shown), which was discovered upon analyzing the metallic powder produced by the thermal decomposition of [Co2(CO)8] in solution in the presence of trioctylphosphane oxide [TOPO, Eq. (1)].This publication has 0 references indexed in Scilit: