Quantum wavepacket dynamics on the BH1Sigma+states
- 14 December 1993
- journal article
- Published by IOP Publishing in Journal of Physics B: Atomic, Molecular and Optical Physics
- Vol. 26 (23) , 4471-4482
- https://doi.org/10.1088/0953-4075/26/23/018
Abstract
We investigate the dynamics of the ground state and the first three singlet 1 Sigma + excited states of BH using the split-operator method. Ab initio calculations show that these states have strong non-adiabatic couplings, resulting in a complex topology of avoided crossing regions and double well potentials. We attempt to find a method to populate the second minimum of B 1 Sigma +, enabling experimental observation of its vibrational states.Keywords
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