Catalytic hydroxylation of benzene over transition-metal substituted hexagonal mesoporous silicas

Abstract
Ti-, V-, Cr-, Mo-, and Mn-substituted hexagonal mesoporous silicas prepared at ambient temperature by electrostatic (S+ XI+) and neutral (S0 I0) surfactant templating pathways are catalytically active for the peroxide hydroxylation of benzene to phenol in the absence of a solvent.

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