Stereochemically divergent pathways for the allylation and crotylation reactions of anti- and syn-β-hydroxy-α-methyl aldehydes with allyl- and crotyltrifluorosilanes
- 1 June 1999
- journal article
- Published by Elsevier in Tetrahedron Letters
- Vol. 40 (25) , 4643-4647
- https://doi.org/10.1016/s0040-4039(99)00730-3
Abstract
No abstract availableKeywords
This publication has 17 references indexed in Scilit:
- Concerning the Synthesis of the Elusive anti,anti-Dipropionate Stereotriad via the Crotylation of β-Hydroxy α-Methyl Aldehydes with (Z)-Crotyltrifluorosilane. Application to the Synthesis of the C(7)−C(16) Segment of ZincophorinThe Journal of Organic Chemistry, 1998
- Directed methallylations as a synthetic route to 1,3-polyolsTetrahedron Letters, 1998
- Stereoselective Synthesis of Alcohols, XLV:1Recent Developments in the Generation of the Stereotriad "D"Synthesis, 1994
- Concerning the diastereofacial selectivity of the aldol reactions of .alpha.-methyl chiral aldehydes and lithium and boron propionate enolatesThe Journal of Organic Chemistry, 1991
- Stereoselective allyl- and crotylboration of alpha-hydroxyketones via neighboring group controlTetrahedron Letters, 1991
- Chemistry of organosilicon compounds. 260. Allylation of .alpha.-hydroxy ketones with allyltrifluorosilanes and allyltrialkoxysilanes in the presence of triethylamine. Stereochemical regulation involving chelated bicyclic transition statesJournal of the American Chemical Society, 1989
- Stereohomogeneous synthesis of (E)- and (Z)-crotyltrifluorosilanes and highly stereoselective allylation of aldehydesTetrahedron Letters, 1989
- Chemistry of organosilicon compounds. 240. Pentacoordinate allylsilicates: characterization and highly stereoselective reaction with aldehydesJournal of the American Chemical Society, 1988
- Regiospecific and highly stereoselective allylation of aldehydes with allyltrifluorosilane activated by fluoride ions.Tetrahedron Letters, 1987
- AlkenylfluorosilanesRussian Chemical Bulletin, 1962