Stereoselective synthesis of crinosterol [(22E,24S)-ergosta-5,22-dien-3β-ol]
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 10,p. 2365-2367
- https://doi.org/10.1039/p19830002365
Abstract
A stereoselective synthesis of crinosterol, (22E,24S)-ergosta-5,22-dien-3β-ol, was developed from (20S)-6β-acetoxy-3α,5-cycle-5α-pregnane-20-carbaldehyde using the Claisen rearrangement of an appropriate precursor of established absolute configuration.This publication has 1 reference indexed in Scilit: