Solvent effects on the absorption spectrum of the perylene-SbCl5 complex
- 1 February 2012
- journal article
- Published by Pleiades Publishing Ltd in Russian Journal of General Chemistry
- Vol. 82 (2) , 300-304
- https://doi.org/10.1134/s107036321202020x
Abstract
The perylene-SbCl5 complex is characterized by two absorption maxima, whose positions depend on the nature of the solvent. The maximum in the region of 19×10−3 cm−1 corresponds to the perylene cationic form and depends on the medium polarity, while another, in the region of 14×10−3 cm−1, corresponding to the perylene-SbCl5 complex, is governed primarily by the ability of the solvent to the electrophilic solvation. However, the quantitative generalization of the data on the frequencies of absorption maxima is only possible using multiparameter equations that take into account various properties of the solvents.Keywords
This publication has 6 references indexed in Scilit:
- Correlation Analysis in Chemistry of SolutionsPublished by Taylor & Francis ,2004
- A semiempirical model for the description of solvent effects on chemical reactionsPublished by Walter de Gruyter GmbH ,1979
- The Influence of the Solvent on Organic ReactivityPublished by Springer Nature ,1972
- Coordination Chemistry in Non-Aqueous SolutionsPublished by Springer Nature ,1968
- The Solvent Effect on the Interaction between Perylene and Antimony PentachlorideBulletin of the Chemical Society of Japan, 1966
- Theory of Solvent Effects on Molecular Electronic Spectra. Frequency ShiftsThe Journal of Physical Chemistry, 1957