A novel synthetic route to peralkylated carborane anions, 1-H-CB9Me9− and 1-H-CB11R11− (R = Me, Et)
- 11 September 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 19,p. 1839-1840
- https://doi.org/10.1039/b004737f
Abstract
Treatment of carborane anions with excess RBr (R = Me, Et) in a sealed Pyrex tube at 200 °C gives peralkylated carborane anions in quantitative yields, which represents the most convenient and the most economic method so far reported in the literature for the preparation of peralkylcarborane anions.Keywords
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