Loosely bonded adducts of plumbocene; structures and solution dynamics of [(η-C5H5)2Pb·tmeda] and [(η-C5H5)2Pb·4,4′-Me2bipy](tmeda = Me2NCH2CH2NMe2, 4,4′-Me2bipy = 4,4′-dimethylbipyridine)
- 1 January 1996
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 16,p. 1977-1978
- https://doi.org/10.1039/cc9960001977
Abstract
The first Lewis-base adducts of a neutral p-block group metallocene, [(η-C5H5)2Pb·tmeda] 1 and [η-C5H5)2Pb·4,4′-Me2bipy] 2, result from the addition of tmeda and 4,4′-Me2bipy to [Pb(η-C5H5)2](1:1 equiv.); X-ray and solution studies reveal that the Lewis bases are only loosely associated to the PbII centres in these complexes.Keywords
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