Charge-transfer in a π-stacked fullerene porphyrin dyad: evidence for back electron transfer in the ‘Marcus-inverted’ region
- 22 February 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 5,p. 373-374
- https://doi.org/10.1039/a909657d
Abstract
The ‘Marcus-inverted’ region for BET in a π–π stacked fullerene–porphyrin dyad was determined based on (i) the photoactivation of an intramolecular ET in a variety of solvents and (ii) the formation of a highly energetic charge-separated stateKeywords
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