Preparation and Properties of some Non-Metallic Derivatives of Pentafluorothiophenol

Abstract
Various non-metallic derivatives of pentafluorothiophenol, containing sulfur bonded to boron, carbon, silicon, germanium, phosphorus, arsenic, antimony, sulfur, and chlorine, have been prepared, mainly from the reaction of Pb(SC6F5)2 with a non-metallic halide, and characterized. The 19F n.m.r. spectra have been examined. The coordinating power of sulfur attached to a C6F5 group is minimal.

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