Structural isomers of a terminal phosphinidene complex

Abstract
The reactions of ArP(Li)(SiMe3)(Ar = 2,4,6-But 3C6H2) with (η5-C5H5)2ZrCl2 and (η5-C5H4Me)2WCl2 afford (η5-C5H5)2Zr(Cl)P(SiMe3)(Ar) and two isomers of composition (η5-C5H4Me)[graphic omitted]Ar)], respectively, the structures of which have been determined.

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