Synthesis of a neoatisiranone, the enantiomer of a ketone obtained by the acid-catalysed rearrangement of isophyllocladene epoxide
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society C: Organic
- p. 1018-1020
- https://doi.org/10.1039/j39710001018
Abstract
The constitution and stereochemistry of a compound obtained by the acid-catalysed rearrangement of isophyllocladene epoxide have been confirmed by a synthesis of its enantiomer from (–)-neoatisirene. In addition, it has been shown that the neoatisiranol (XII) on dehydration undergoes skeletal rearrangement to the olefin (XIII).Keywords
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