Absolute rate and temperature dependence of the reaction between chlorine (2P) atoms and methane
- 1 July 1978
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 69 (1) , 214-218
- https://doi.org/10.1063/1.436388
Abstract
The absolute rate of reaction Cl(2P)+CH4→HCl+CH3 was determined between 220 and 423 K using the discharge flow–resonance fluorescence technique. Evidence of curvature is observed in the Arrhenius plot. The data are best fitted by the following Arrhenius expressions: The present results are compared with earlier absolute rate measurements.This publication has 19 references indexed in Scilit:
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