Kinetische Untersuchungen zur Pyrolyse von Mono‐n‐alkyl‐cyclohexanen
- 1 January 1983
- journal article
- research article
- Published by Wiley in Journal für Praktische Chemie
- Vol. 325 (1) , 66-74
- https://doi.org/10.1002/prac.19833250109
Abstract
Kinetic Investigations of the Pyrolysis of Mono‐n‐alkyl‐cyclohexanesThe thermal decomposition of cyclohexane and six mono‐n‐alkylcyclohexanes was studied kinetically in a metallic laboratory tubular reactor at 650 to 850°C and atmospheric pressure.Kinetic parameters were found to be a function of length of the alkylic side chain. A comparison with analogous parameters of n‐paraffins and the unsubstituted cyclohexane allowed the conclusion that CC‐scission in the alkylic chain is the initial reaction in pyrolysis of n‐alkylcyclohexanes followed by radical attacks to all CH‐bonds of the feed molecules.Keywords
This publication has 5 references indexed in Scilit:
- Untersuchungen über den Thermischen Zerfall von n‐Dodecylcyclopentan in der GasphaseJournal für Praktische Chemie, 1982
- Thermal stability of cyclohexane and 1‐hexeneInternational Journal of Chemical Kinetics, 1978
- Thermal Decomposition of Methylcyclohexane in the Presence of n-CetaneThe Journal of the Society of Chemical Industry, Japan, 1966
- Homogenous thermal decomposition of some cyclic hydrocarbonsTransactions of the Faraday Society, 1939
- Kinetics of Dissociation of Typical Hydrocarbon Vapors1Journal of the American Chemical Society, 1933