Reaction of transition-metal complexes with hydroperoxides: oxidation of carbonyl, phosphine, and carbon ligands
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 369-370
- https://doi.org/10.1039/c39760000369
Abstract
[Rh(CO)Cl(PPh3)2], [Ir(CO)Cl(PPh3)2], and [{Rh(CO)2Cl}2] react with ButO2H to give CO2 in what appears to be a stoicheiometric reaction; with m-ClC6H4CO3H the carbon-metal bond in [MCl(CH2Ph)(PPh3)2](M = Pt or Pd) is cleaved to give m-ClC6H4CO2CH2Ph, and di-µ-chloro-bis{endo-η-2,3;η-5-(6-methoxybicyclo[2.2.1]hept-2-enept-2-enepalladium(II)} yields a methoxytricyclo[2.2.1.0]-heptyl m-chlorobenzoate.Keywords
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