The Synthesis of Some Mercurial Derivatives of Simple Sugars
- 1 January 1965
- journal article
- research article
- Published by Wiley in Israel Journal of Chemistry
- Vol. 3 (3) , 107-111
- https://doi.org/10.1002/ijch.196500027
Abstract
A number of organomercurials have been produced by oxymercuration of 3,4,6‐tri‐O‐acetyl‐D‐glucal and 2,3,4,6‐tetra‐O‐acetyl‐2‐hydroxy‐D‐glucal followed by replacement of mercury‐bound acetate with a variety of ions. Data collected in connection with investigating the structure of one of the products suggest that reductive demercuration by NaBH4 may proceed with retention of configuration of the mercury‐bound carbon atom.Keywords
This publication has 6 references indexed in Scilit:
- Oxymercuration of D-Glucal and Its 3,4,6-TriacetateJournal of the American Chemical Society, 1962
- 190. The methoxymercuration of D-glucal and tri-O-acetyl-D-glucal: a new route to 2-deoxyglycopyranosidesJournal of the Chemical Society, 1962
- The Addition Compounds of Olefins with Mercuric Salts.Chemical Reviews, 1951
- Alpha and beta methyl lyxosides, mannosides, gulosides, and heptosides of like configurationJournal of Research of the National Bureau of Standards, 1940
- CCCLI.—The structure of carbohydrates and their optical rotatory power. Part IV. Derivatives of α- and β-methylmannopyranosideJournal of the Chemical Society, 1930
- A COMPARISON OF THE OPTICAL ROTATORY POWERS OF THE ALPHA AND BETA FORMS OF CERTAIN ACETYLATED DERIVATIVES OF GLUCOSE.Journal of the American Chemical Society, 1915