Molecular Structure of Bromoform

Abstract
The structure of bromoform has been evaluated entirely from microwave spectroscopy. The B0 values in Mc/s of the isotopic species studied are: 1247.61±0.025 for CHBr379; 1217.30±0.025 for CHBr381; 1239.45±0.025 for CDBr379; 1209.51±0.025 for CDBr381. These constants yield the structure as follows: dCH=1.07A±0.01A, dCBr=1.930A±0.003A, angle BrCBr=110°48′±16′.

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