A general treatment of enhanced nucleophilic reactivity
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 522-523
- https://doi.org/10.1039/c39720000522
Abstract
A semi-theoretical expression for the “α-effect” is derived and applied to the reactions of oximate, hydroxamate, and peroxide ions with benzyl halides and p-nitrophenyl acetate, and of a series of heterocyclic molecules with 2,4-dinitrophenyl acetate.Keywords
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