Do paramagnetic platinum metal hydrides really exist? A reinvestigation of the synthesis and magnetochemical properties of Ir(H)x(Cl)2(P-i-Pr3)2 (1). Syntheses and crystal structure determinations of trans-Ir(H)(Cl)2(CO)(P-i-Pr3)2 (2), cis-Ir(H)(Cl)2(CO)(P-i-Pr3)2 (4) and trans-Ir(Cl)(CO)(P-i-Pr3)2 (5)
- 1 May 1997
- journal article
- Published by Elsevier in Inorganica Chimica Acta
- Vol. 258 (2) , 169-181
- https://doi.org/10.1016/s0020-1693(96)05498-9
Abstract
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This publication has 15 references indexed in Scilit:
- Reaction of molecular hydrogen (H2) with chlorohydridoiridium phosphines IrHCl2P2 (P = PPr-iso3 or PBu-tert2Ph): stereoelectronic control of the stability of molecular H2 transition metal complexesJournal of the American Chemical Society, 1993
- NMR spectra and the products of interaction of iridium monohydrides IrHCl2L2 (LP(CH(CH3)2)3 and P(c-C6H11)3) with molecular hydrogenInorganica Chimica Acta, 1990
- Synthesis of ruthenium and iridium polyhydride complexes under conditions of phase transfer catalysisJournal of Organometallic Chemistry, 1990
- Stable paramagnetic dihydrido complexes of iridium(IV): synthesis, x-ray crystal structure, and behavior in solution of IrIV(H)2(Cl)2(P-iso-Pr3)2 (1) and IrIV(H)2(Cl)2(PCy3)2 (2)Inorganic Chemistry, 1989
- Photochemical reactivity of 2[IrIIIHCl2(PPri3)2]·H2. Formation of monohydrido isomers of IrIIIand evidence of photoinduced oxidative addition of H2, to IrIIIJ. Chem. Soc., Dalton Trans., 1989
- Unusual Behavior of the Stable Paramagnetic Dihydridoiridium(IV) Complex[Ir(H)2(Cl)2(iPr3P)2] in SolutionAngewandte Chemie International Edition in English, 1986
- Synthesis and x-ray crystal structure of the stable paramagnetic iridium dihydrido complex Ir(H)2(Cl)2(P-iso-Pr3)2Journal of the American Chemical Society, 1986
- Basische metalleJournal of Organometallic Chemistry, 1985
- Hydride complexes of the transition metalsChemical Reviews, 1972
- Chlorotris(triphenylphosphine)iridium(I) and related complexes. Oxidative addition reactions and hydrogen abstraction from the coordinated ligandJournal of the American Chemical Society, 1969