Synthesis of ruthenium(III) and osmium(III) porphyrin mono-alkyl and -aryl complexes and of a noval six-coordinate asymmetrically substituted ruthenium(IV) porphyrin complex, [Ru(oep)(Ph)(Me)]
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 11-12
- https://doi.org/10.1039/c39940000011
Abstract
MIII porphyrin monoalkyl complexes, [M(oep)(Me)](M = Ru, Os), are produced by methylation of the monomer monoanion, [M(oep)]–, or by additaion of MeMgBr to the [M(oep)]2 2+ dimer dication; the RuIII monophenyl complex, [Ru(oep)(Ph)], can be reduced by one electron and treated with Mel to give the six-coordinate asymmetrically substituted RuIV porphyrin complex, [Ru(oep)(Ph)(Me)].Keywords
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