An experimental study of the gas-phase reactions of the NO3 radical with pent-1-ene, hex-1-ene and hept-1-ene
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Physical Chemistry Chemical Physics
- Vol. 1 (11) , 2681-2685
- https://doi.org/10.1039/a900870e
Abstract
Rate coefficients for the reactions between the NO3 radical and pent-1-ene (k1), hex-1-ene (k2) and hept-1-ene (k3) have been determined at T=296±1 K and P=759±7 Torr by a relative-rate method using the reaction between the NO3 radical and but-1-ene (k4) as the reference reaction. The values of the rate constants measured were k1=(1.51±0.54)×10-14 cm3 molecule-1 s-1, k2=(1.85±0.66)×10-14 cm3 molecule-1 s-1, k3=(2.06±0.62)×10-14 cm3 molecule-1 s-1 and the value of the reference rate constant was k4=(1.35±0.41)×10-14 cm3 molecule-1 s-1.Keywords
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