The use of U.V. absorption spectra for the determination of configurations of some aromatic oximes
- 1 January 1959
- journal article
- research article
- Published by Wiley in Recueil des Travaux Chimiques des Pays-Bas
- Vol. 78 (10) , 739-753
- https://doi.org/10.1002/recl.19590781003
Abstract
The U.V. absorption spectra of a series of benzophenone oximes are discussed. Notwithstanding relatively small differences in absorption of the isomers, incontestable conclusions as regards configurations can be drawn, even if only one of the conceivable isomers is available. The results agree with what might be expected on the assumption that the Beckmann rearrangement proceeds via an anti‐migration.Keywords
This publication has 17 references indexed in Scilit:
- Steric effects in the electronic spectra of substituted benzophenonesSpectrochimica Acta, 1957
- 204. A new mechanism for the Beckmann rearrangement of ketoximesJournal of the Chemical Society, 1956
- Furans. I. The Ultraviolet Absorption of Isomeric FuraldoximesJournal of the American Chemical Society, 1946
- Zur Kenntnis der Beckmannschen UmlagerungBerichte der deutschen chemischen Gesellschaft (A and B Series), 1921
- Über N‐ und O‐Methyläther von Ketoximen. Die 4 isomeren Methyläther des p‐Tolyl‐phenyl‐ketoximsEuropean Journal of Inorganic Chemistry, 1918
- Über Bildung von Indazolkörpern aus orthomethylierten AnilinbasenEuropean Journal of Inorganic Chemistry, 1908
- Ueber Oxime der unsymmetrischen Ketone mit zwei gleichnamigen KernenEuropean Journal of Inorganic Chemistry, 1903
- Décomposition spontanée de la benzophénone‐oximeRecueil des Travaux Chimiques des Pays-Bas, 1894
- Décomposition spontanée de la benzophénone‐oximeRecueil des Travaux Chimiques des Pays-Bas, 1894
- Ueber den Einfluss substituirender Radicale auf die Configuration aromatischer KetoximeEuropean Journal of Inorganic Chemistry, 1891