A Readily Available and User-Friendly Chiral Catalyst for Efficient Enantioselective Olefin Metathesis
- 17 April 2001
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 40 (8) , 1452-1456
- https://doi.org/10.1002/1521-3773(20010417)40:8<1452::aid-anie1452>3.0.co;2-g
Abstract
No glove box required! A new chiral catalyst for olefin metathesis is prepared from commercially available materials and is equally or more effective and selective than the previous systems. The new user‐friendly catalyst can be prepared in situ (see scheme, Ar=aryl, Tf=trifluoromethanesulfonyl), isolation not needed, outside of a glove box, and delivers reactivity and enantioselectivity levels formerly available only through multiple catalysts.Keywords
This publication has 17 references indexed in Scilit:
- Enantioselective Synthesis of Unsaturated Cyclic Tertiary Ethers By Mo-Catalyzed Olefin MetathesisJournal of the American Chemical Society, 2001
- Catalytic Asymmetric Olefin MetathesisChemistry – A European Journal, 2001
- Olefinmetathese und mehrAngewandte Chemie, 2000
- Tandem Catalytic Asymmetric Ring-Opening Metathesis/Ring-Closing MetathesisJournal of the American Chemical Society, 2000
- Tandem Catalytic Asymmetric Ring-Opening Metathesis/Cross MetathesisJournal of the American Chemical Society, 1999
- Chiral Mo−Binol Complexes: Activity, Synthesis, and Structure. Efficient Enantioselective Six-Membered Ring Synthesis through Catalytic MetathesisJournal of the American Chemical Society, 1999
- Mo-Catalyzed Asymmetric Synthesis of Dihydrofurans. Catalytic Kinetic Resolution and Enantioselective Desymmetrization through Ring-Closing MetathesisJournal of the American Chemical Society, 1998
- Kinetic ResolutionPublished by Wiley ,1988
- Host-guest complexation. 23. High chiral recognition of amino acid and ester guests by hosts containing one chiral elementThe Journal of Organic Chemistry, 1981
- Ueber Condensationen von Isoamylen und von Styrol mit PhenolenEuropean Journal of Inorganic Chemistry, 1891