Pyrolysis of phenyl 2,2,2-trideuterioacetate. Evidence against a concerted mechanism
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 9,p. 357-358
- https://doi.org/10.1039/c39740000357
Abstract
Pyrolysis of phenyl 2,2,2-trideuterioacetate yields phenol with no ortho-deuterium, indicating that the reaction does not involve a concerted sigmatropic rearrangement.Keywords
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