C−H Bonds Are Not Elongated by Coordination to Lanthanide Metals: Single-Crystal Neutron Diffraction Structures of (C5Me5)Y(OC6H3tBu2)CH(SiMe3)2at 20 K and (C5Me5)La{CH(SiMe3)2}2at 15 K
- 28 January 1999
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 121 (6) , 1381-1382
- https://doi.org/10.1021/ja983068b
Abstract
No abstract availableThis publication has 12 references indexed in Scilit:
- Alkoxides as ancillary ligands in organolanthanide chemistry: synthesis of, reactivity of, and olefin polymerization by the .mu.-hydride-.mu.-alkyl compounds [Y(C5Me5)(OC6H3tBu2)]2(.mu.-H)(.mu.-alkyl)Organometallics, 1994
- Mono(pentamethylcyclopentadienyl) complexes of cerium(III). Synthesis, molecular structure, thermal stability, and reactivity of (C5Me5)CeX2 (X = 2,6-di-tert-butylphenoxo, CH(SiMe3)2, and N(SiMe3)2) complexesOrganometallics, 1989
- The first salt- and solvent-free monocyclopentadienyl lanthanide dialkyl complex. X-ray structure determinations of La(.eta.5-C5Me5)[CH(SiMe3)2]2 and of its tetrahydrofuran adduct: compounds containing agostic silicon-carbon bondsOrganometallics, 1989
- Bis(pentamethylcyclopentadienyl) complexes of cerium(III). Crystal structure of (C5Me5)2CeCH(SiMe3)2Organometallics, 1988
- Silicon-carbon agostic interaction with titanium: origin of alkenyl group distortion in Ti[C(SiH2CH3):CH2]X2+. An ab initio MO studyJournal of the American Chemical Society, 1988
- Carbon‐Hydrogen‐Transition Metal BondsPublished by Wiley ,1988
- Synthesis of monomeric permethylyttrocene derivatives. The crystal structures of Cp2*YN(SiMe3)2 and Cp2*YCH(SiMe3)2Organometallics, 1986
- Highly reactive organolanthanides. Synthesis, chemistry, and structures of 4f hydrocarbyls and hydrides with chelating bis(polymethylcyclopentadienyl) ligandsJournal of the American Chemical Society, 1985
- Highly reactive organolanthanides. Systematic routes to and olefin chemistry of early and late bis(pentamethylcyclopentadienyl) 4f hydrocarbyl and hydride complexesJournal of the American Chemical Society, 1985
- Organometallic compounds of Group III. Part 41. Direct observation of the initial insertion of an unsaturated hydrocarbon into the titanium-carbon bond of the soluble Ziegler polymerization catalyst Cp2TiCl2-MeAlCl2Journal of the American Chemical Society, 1985