Co-ordination compounds of organotin halides with 4,4′-bipyridyl
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1578-1580
- https://doi.org/10.1039/j19670001578
Abstract
It is shown that 4,4′-bipyridyl forms stable 1 : 1 adducts with organotin halides of the types RnSnX4–n where n= 1,2, or 3; with stannic chloride a 2 : 1 complex is formed. 4-Phenylpyridine gives a 2 : 1 adduct with dibutyltin dichloride and a 1 : 1 adduct with triphenyltin chloride. The infrared spectra of the compounds have been measured and the Sn–Cl and Sn–Ph bands assigned. The structures of the adducts are discussed.Keywords
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