Synthesis of Pentamethyl-monohydro[60]fullerene C60Me5H and Its Use as Cyclopentadienyl-Type Ligand Precursor
- 1 March 2000
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 29 (3) , 270-271
- https://doi.org/10.1246/cl.2000.270
Abstract
Pentamethyl-monohydro[60]fullerene C60Me5H has been synthesized through five-fold addition of methylcopper reagent to C60. The anion C60Me5− generated by deprotonation of C60Me5H forms organometallic complexes with K+ and Tl+ ions with stronger metal-carbon interaction than that in the corresponding pentaphenylated ligand C60Ph5−.Keywords
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