Remarkable Reaction of Hetero-S-Block-Metal Amides with Molecular Oxygen: Cationic (NMNMg)2 Ring Products (M=Li or Na) with Anionic Oxo or Peroxo Cores
- 4 December 1998
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 37 (22) , 3180-3183
- https://doi.org/10.1002/(sici)1521-3773(19981204)37:22<3180::aid-anie3180>3.0.co;2-d
Abstract
Deliberate treatment of solutions of amines with molecular oxygen has given rise to magnesium‐substituted derivatives of classical alkali metal amide ring structures (NMNMg)2 (M=Li or Na), but with oxo or peroxo cores. The picture shows the structure of the sodium compound [{(Me3Si)2N}4Na2Mg2(O2)x(O)y].This publication has 0 references indexed in Scilit: