Nematic-Wetted Colloids in the Isotropic Phase: Pairwise Interaction, Biaxiality, and Defects
- 23 April 2001
- journal article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 86 (17) , 3915-3918
- https://doi.org/10.1103/physrevlett.86.3915
Abstract
We calculate the interaction between two spherical colloidal particles embedded in the isotropic phase of a nematogenic liquid. The surface of the particles induces wetting nematic coronas that mediate an elastic interaction. In the weak wetting regime, we obtain exact results for the interaction energy and the texture, showing that defects and biaxiality arise, although they are not topologically required. We evidence rich behaviors, including the possibility of reversible colloidal aggregation and dispersion. Complex anisotropic self-assembled phases might be formed in dense suspensions.Keywords
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This publication has 18 references indexed in Scilit:
- Cellular solid behaviour of liquid crystal colloids 2. Mechanical propertiesThe European Physical Journal E, 2001
- Defect-Induced Phase Separation in Dipolar FluidsScience, 2000
- Orientational wetting and capillary nematization of hard-rod fluidsEurophysics Letters, 2000
- Suspension of spherical particles in nematic solutions of disks and rodsPhysical Review E, 1999
- Direct Measurement of Colloidal Forces in an Anisotropic SolventPhysical Review Letters, 1997
- Novel Colloidal Interactions in Anisotropic FluidsScience, 1997
- Solvent-Induced Phase Separation in Colloidal FluidsPhysical Review Letters, 1995
- Focal conic faceting in smectic-A liquid crystalsJournal de Physique II, 1991
- Wall-Induced Pretransitional Birefringence: A New Tool to Study Boundary Aligning Forces in Liquid CrystalsPhysical Review Letters, 1979
- Phase Transition in Surface-Aligned Nematic FilmsPhysical Review Letters, 1976