Partial Oxidation of Ethane over Boron Oxide Added Catalysts

Abstract
B2O3–Al2O3, B2O3–MgO, B2O3–La2O3, and B2O3–P2O5 are selective catalysts for the partial oxidation of ethane. Among these catalysts, B2O3(30wt%)-added Al2O3 showed the highest catalytic activity in the formations of acetaldehyde (yield 1.03%) and ethylene (14.6%). Acetaldehyde is formed not via ethylene but directly from ethane. The formations of ethylene and acetaldehyde occur on different active sites.

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